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" Let us now return to the mine. The deeper we sink down into the reef we find that while the richness of the ore may remain constant, the proportion of free gold—that is, amalgamable gold, becomes smaller and smaller, while the proportion of gold-bearing sulphides becomes greater and greater till we come to the water level, where it often happens that the free gold leaves entirely and becomes wholly refractory—that is, non-amalgamable. The water level is generally regarded as the point where the atmospheric and weather influences cease, and that down to that point the rain-water has penetrated and gradually washed away the oxidisable base metals, leaving the inert gold in the crevices of the equally inert quartz, whereas the ore found below the water level, not having been subjected to oxidising influences, retains all its metals untouched and unchanged. " An interesting problem now presents itself : An ore consisting of a complex mixture of silica and the various compounds of iron, copper, lead, zinc, antimony, arsenic, and sulphur (for convenience I will include all these compounds under the general term sulphides), and gold in the proportion of 10,000 parts of silica and sulphides to one part of gold, is very much richer than the average auriferous ore, and the question is, how can we best separate the one from the 10,000 ? Under favourable circumstances, the gold and the useful metals may be recovered by smelting, but these favourable circumstances, which are proximity of the gold-mine to coal, clay, limestone, and other fluxes, are quite exceptional, as auriferous reefs are generally found in primary formations. As before implied, chlorination is frequently inapplicable—no attempt is ever made to chlorinate gold-ore containing an appreciable qnantity oi lead—and where applicable is always troublesome and never cheap. When this question presented itself to Dr. Forrest and myself, we tried to find some solvent which, unlike chlorine and mercury, would have a stronger affinity for gold than for sulphides. Acting on this principle, we drew out a list of all probable or possible solvents fulfilling this condition. This list included cyanides, and we found that these salts solved the problem. " Our experiments were conducted first on a small scale, and on ores of all kinds and from all mines in all parts of the world. The result of these small trials was so satisfactory that we gradually worked from less to more, and in no longtime larger quantities were worked, and now the process is in, or on the eve of being put in, operation in all quarters of the globe. I have now much pleasure in describing the method of working most generally applicable. The ore is ground to about the fineness of sea-sand. If, instead of ore, we are working tailings from the amalgamation process, these are generally not reground, but treated as delivered. The finely-divided material is mixed with a solution of cyanide, say cyanide of potassium, containing on an average o'4 per cent, of cyanogen as the cyanide of potassium or other alkali or alkaline earth. The ore and solution are stirred together for about six hours, more or less, this being the average time required to dissolve the gold; in practice the time required is determined by direct experiment. When the gold is known to be dissolved, the pulp is discharged into an ordinary filtering-tank, where the filtration may, if necessary, be assisted by suction, and where the ore is washed by water or by the waste cyanide solution from a previous operation. The ore, after treatment with cyanide solution, is unchanged to the eye, as almost nothing but the imperceptible proportion of gold present has been removed. The gold now being in solution, the next object is to get it precipitated, and here we encounter a serious difficulty. Gold and cyanogen have such a strong mutual affinity, that it is difficult to get any substance that will separate them. The gold cannot be precipitated by any ordinary method, such as the use of ferrous sulphate or oxalic acid; even sulphuretted hydrogen and sulphide of sodium will not precipitate gold from its cyanide solution, though they precipitate silver. On referring to books on electro-gilding, we got no assistance, as the invariable method given for the recovery of gold from cyanide solutions was, evaporate to dryness and fuse the residue. We had noticed, however, by experiment, that zinc precipitated gold very feebly, and tried this in the same way that copper is precipitated from its ordinary solutions by scrap iron, but scrap zinc had no effect; then granulated zinc was tried, with a most imperfect and disappointing result; then heating in presence of scrap and granulated zinc; but this had only the effect of forming urea, and assisting the precipitation very little indeed. Further, we tried zinc dust, but still there was no success ; finally, we prepared some zinc in a form like sawdust, porous, and with a large surface of bright metal. On allowing the cyanide of gold solution to trickle through a mass of the zinc, we found that it trickled out gold free, and better still, we found that the action became more vigorous and pronounced after a portion of the gold had been precipitated on it, doubtless as gold and zinc formed together a more powerful electro-chemical precipitant than zinc by itself. An arrangement of a porous mass of zinc like a sponge formed a chemical filter, which at once precipitated and collected the precious metal; indeed, so like an ordinary water-purifying device was this zinc filter, that many non-technical visitors formed and held tenaciously to the idea that the gold was in suspension in the cyanide solution, and the zinc was used merely because of its durability. " Improvements in detail were made in the direction of increasing the surface and decreasing the weight of the zinc, till now we have it in threads, lib. of which occupies about 2gal. measure. The zinc in this form is possessed of enormous chemical activity, of which the strongest and most direct evidence is the fact that it burns in the air like thin shavings of wood. When the gold has been deposited, it is necessary to separate it from the excess of zinc present. The filiform structure of the zinc, and the exceedingly fine powder, as which the gold is deposited, render this an easy matter. The filiform mass of zinc with gold powder adhering is vigorously shaken in water, when the gold falls off and the fibrous particles of the zinc may be collected in a sieve. The gold settles easily, is collected, and fused directly into bullion. " Having now described the chief points in the process from the technical standpoint, let us look at the purely chemical aspect it presents. Reference has already been made to the fact that a cyanide solution acts on the gold in ores in preference to the sulphides of base metals with which it may be combined or associated. This selective action is the keystone of the whole process. It is known that metallic gold is dissolved by a cyanide. It is also known that sulphides of copper, zinc, and iron artifically prepared are readily acted on by a cyanide solution, but we found a very
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